Two photonic crystal fiber structures with quad-core have been investigated in this paper. Both the structures are geometrically similar but have different background materials. Both PCF structures exhibit very high birefringence. However, structure with silica background material reports birefringence of the order 10−2. It is to be noted that, this PCF structure has also shown zero dispersion behavior over a wide range of telecommunication wavelength. Moreover, the other structure with lead silicate as background material has also reported very low dispersion. Thus both the PCF structures simulated show ability to mitigate the effect of polarized mode dispersion. Besides this, other propagation characteristics like confinement loss, normalized frequency and non linear coefficient have been reported.