Optical Wireless Communication (OWC) is widely used in current broadband access markets. This is due to the usage of optical radiation through free space for transmission. OWC employs Intensity Modulation with Direct Detection (IMDD) to modulate the intensity of the signal in order to transmit information. This offers a flexible networking solution. OWC systems that operate in the visible band region (390-750 nm) are referred to as Visible Light Communication. VLC has a dual purpose of illumination and communication system. VLC uses On-Off Keying (OOK) and Pulse Position Modulation (PPM). But recently, a noticeable increase in the use of a number of other modulation techniques such as Digital Pulse Interval Modulation (DPIM) and Dual-header Pulse Interval Modulation (DH-PIM) to improve the efficiency in terms of both the bandwidth and power has been observed. This paper concentrates on baseband pulse time modulation techniques that are used to modulate data for OWC and compares OOK, PPM, DH-PIM and DPIM techniques with respect to their spectral efficiency, optical power, bandwidth, transmission capacity, packet transmission rates and peak average power ratio (PAPR).