Home Di- ortho-beryllated Carbodiphosphorane: A Compound with a Metal-Carbon Double Bond to an Element of the s-Block

Publications

Di- ortho-beryllated Carbodiphosphorane: A Compound with a Metal-Carbon Double Bond to an Element of the s-Block

Author : Dr Sudip Pan

Year : 2020

Publisher : American Chemical Societyservice@acs.org

Source Title : Organometallics

Document Type :

Abstract

Double bonds have been realized for a wide variety of elements in the p-, d-, and f-blocks. However, no s-block metal complexes with a double bond have been identified. Here we report the synthesis and characterization of a di-ortho-beryllated carbodiphosphorane, which exhibits a double dative Be═C bond. This species shows an unprecedented bonding situation at the metal center, which was extensively analyzed by experimental and computational means.