C-S bond cleavage by cobalt: Synthesis, characterization and crystal structure determination of 1,2-di-(o-salicylaldiminophenylthio)ethane and its CO(III) product with C-S bond cleaved fragments

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C-S bond cleavage by cobalt: Synthesis, characterization and crystal structure determination of 1,2-di-(o-salicylaldiminophenylthio)ethane and its CO(III) product with C-S bond cleaved fragments

Author : Dr Chebrolu Pulla Rao

Year : 2002

Source Title : Inorganic Chemistry Communications

Document Type : Article

Link

DOI

https://doi.org/10.1016/S1387-7003(02)00522-1

Web

https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=0036724119&origin=inward

Abstract

1,2-Di-(o-salicylaldiminophenylthio)ethane reacts with Co(II) salts to form a complex with oxidative cleavage of the C-S bond, to result in the formation of a Co(III) complex of the cleaved ligands. © 2002 Elsevier Science B.V. All rights reserved.