This paper presents an exhaustive search approach to determine the best location and size of PV placement for power loss minimization of radial distribution networks. In this approach, the network power loss is determined by placing PV in each location, one at a time, and the size of PV in the same location is varied between 10 and 300 kW with an increment of 10 kW. The combination of location and size of PV which provides the minimum network power loss can be the best location and size of PV for power loss minimization of radial distribution networks. The forward–backward sweep load flow algorithm is used to incorporate the PV model. The 33-bus radial distribution network is used to demonstrate the approach. The simulation results show that the placement of a suitable size of PV in some specific locations significantly reduces the network power loss.