Crystal structure of a compact three-dimensional metal–organic framework based on Cs+ and (4,5-dicyano-1,2-phenylene)bis(phosphonic acid),

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Crystal structure of a compact three-dimensional metal–organic framework based on Cs+ and (4,5-dicyano-1,2-phenylene)bis(phosphonic acid),

Crystal structure of a compact three-dimensional metal–organic framework based on Cs+ and (4,5-dicyano-1,2-phenylene)bis(phosphonic acid),

Year : 2016

Publisher : Wiley

Source Title : Acta. Cryst.Section E:  Crystallographic Communication

Document Type :

Abstract

The three-dimensional metal–organic framework compound prepared from Cs+ and the organic linker 4,5-di­cyano-1,2-phenyl­ene)bis­(phospho­nic acid is based on an irregular CsO8N2 coordination center comprising a single monodentate hydro­nium O-atom donor, together with multiple bridging links to the two phospho­nate O-atom donors and to the two nitrile N-atom donors.