Abstract
Herein, we are demonstrating the use of a binder-free electrode
based on copper–molybdenum–sulfide nanostructures grown on
nickel foam (CMS/Ni) as a novel negative electrode for supercapacitors.
The cyclic voltammetry and charge–discharge analyses
reveal the pseudocapacitive nature of the CMS/Ni electrode with a
high specific capacity of 633 mAh g−1 (∼20-fold higher than the
binder-based CMS electrode) which is mainly due to their superior
electronic conductivity and short ion transport pathways.
Furthermore, the fabricated symmetric supercapacitor using the
CMS/Ni electrode delivered a high device capacitance (265.62 F g−1),
high energy density (23.61 Wh kg−1) and long cycle-life. The results
ensure that the CMS/Ni binder-free electrode will be a promising
negative electrode for high-performance supercapacitors.