Nitrogen and phosphorous co-doped graphitic carbon encapsulated ultrafine OsP2 nanoparticles: a pH universal highly durable catalyst for hydrogen evolution reaction

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Nitrogen and phosphorous co-doped graphitic carbon encapsulated ultrafine OsP2 nanoparticles: a pH universal highly durable catalyst for hydrogen evolution reaction

Nitrogen and phosphorous co-doped graphitic carbon encapsulated ultrafine OsP2 nanoparticles: a pH universal highly durable catalyst for hydrogen evolution reaction

Year : 2019

Publisher : Royal Society of Chemistry

Source Title : Chemical Communications

Document Type :

Abstract

The synthesis is described of a pH-universal hydrogen evolution electrocatalyst based on N and P co-doped graphitic carbon encapsulated OsP2 (OsP2@NPC) nanoparticles of 1.8 nm size for the electrocatalytic hydrogen evolution reaction (HER). Our OsP2-based catalyst is catalytically active at all pH values and delivers the benchmark current density of 10 mA cm−2 at an overpotential of 46, 90 and 144 mV in acidic, alkaline and neutral pH, respectively.