Abstract
The ever-growing demand for energy storage devices necessitates the development of
novel energy storage materials with high performance. In this work, copper molybdenum
sulfide (Cu2MoS4) nanostructures were prepared via a one-pot hydrothermal method and
examined as an advanced electrode material for supercapacitor. Physico-chemical characterizations
such as X-ray diffraction, laser Raman, field emission scanning electron
microscope with elemental mapping, and X-ray photoelectron spectroscopy analyses
revealed the formation of I-phase Cu2MoS4. Electrochemical analysis using cyclic voltammetry
(CV), charge-discharge (CD) and electrochemical impedance spectroscopy (EIS)
showed the pseudocapacitive nature of charge-storage via ion intercalation/deintercalation
occurring in the Cu2MoS4 electrode. The Cu2MoS4 electrode delivered a specific
capacitance of 127 F g1 obtained from the CD measured using a constant current
density of 1.5 mA cm2. Further, Cu2MoS4 symmetric supercapacitor (SSC) device delivered
a specific capacitance of 28.25 F g1 at a current density of 0.25 mA cm2 with excellent rate
capability. The device acquired high energy and power density of 3.92 Wh kg1 and
1250 W kg1, respectively. The Nyquist and Bode analysis further confirmed the pseudocapacitive
nature of Cu2MoS4 electrodes. The experimental results indicate the potential
application of Cu2MoS4 nanostructures as a novel electrode material for energy storage
devices.