Ultrafast-Versatile-Domestic-Microwave-Oven Based Graphene Oxide Reactor for the Synthesis of Highly Efficient Graphene Based Hybrid Electrocatalysts

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Ultrafast-Versatile-Domestic-Microwave-Oven Based Graphene Oxide Reactor for the Synthesis of Highly Efficient Graphene Based Hybrid Electrocatalysts

Ultrafast-Versatile-Domestic-Microwave-Oven Based Graphene Oxide Reactor for the Synthesis of Highly Efficient Graphene Based Hybrid Electrocatalysts

Year : 2018

Publisher : American Chemical Society

Source Title : ACS Sustainable Chemistry & Engineering

Document Type :

Abstract

When solid graphene oxide (GO) is treated with microwave, it generates a huge amount of heat followed by reduction and exfoliation. This can be used as a high temperature reactor for ultrafast and in situ synthesis of reduced graphene oxide (rGO) based hybrids within 60 s in an open atmosphere. rGO based hybrids such as Fe3C-G@rGO, Co-Fe3C-G@rGO, Fe-Fe3C-NG@rGO, CoO@rGO, and Pt@rGO (G represents graphene, and NG represents N-doped graphene) have been synthesized by simply mixing appropriate precursors with GO and treating with microwave. The experiments require neither any external high temperature reactors/furnaces nor any chemical reagents or solvents. Then, rGO based hybrids have been exploited for oxygen evolution reaction (OER), oxygen reduction reaction (ORR), and methanol oxidation activity. CoO@rGO and Co-Fe3C-G@rGO show outstanding OER performances with …